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Beilstein J. Org. Chem. 2015, 11, 2795–2804, doi:10.3762/bjoc.11.300
Graphical Abstract
Figure 1: Examples of olefin metathesis ruthenium catalysts.
Figure 2: Selected ruthenium metathesis catalyst bearing chromanyl moieties.
Scheme 1: Synthesis of the new NHC precursor. Reagents and conditions: a) HNO3, CH2Cl2, 0 °C, 58%; b) HOCH2SO...
Scheme 2: CM with electron-deficient olefin.
Scheme 3: Possible products of metathesis reaction between diene and alkene.
Figure 3: π-Complex and rutenacyclobutane intermediate with a five-membered ring chelate.
Scheme 4: CM reaction of β-carotene and retinyl acetate with ethyl (2E,4Z/E)-3-methylhexa-2,4-dienoate. React...
Figure 4: Numbering of carbon atoms in the chromanyl moiety.
Beilstein J. Org. Chem. 2015, 11, 1893–1901, doi:10.3762/bjoc.11.204
Scheme 1: ROCM reactions of 7-oxanorbornene.
Figure 1: Chemical structures of catalysts [Ru]1–6 used in this work.
Scheme 2: Metathesis products of exo- and endo-7-oxabicyclo[2.2.1]hept-5-en-2-carbonitriles (1 and 2) with al...
Figure 2: Representative GC chromatograms recorded from crude reaction mixtures described in Table 1: a) entry 1 and...
Scheme 3: The plausible mechanism of the formation of ROCM and ROMP products from exo- or endo-7-oxabicyclo[2...
Figure 3: Numbering of carbon atoms in cross metathesis products.